Reversibility of al-kaolin and al-humic aggregates monitored by stable diameter and size distribution

The reversibility of aggregates during flocculation was investigated. The stable diameter (d) and the power law slope coefficient of the particle size distribution (β) were applied to follow re-formation after breakage. A non-intrusive image-based technique was used for monitoring flocs. Aggregates...

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Detalhes bibliográficos
Autores: Moruzzi, Rodrigo Braga [UNESP], da Silva, Pedro Augusto Grava [UNESP]
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2018
País:Brasil
Recursos:Universidade Estadual Paulista (UNESP)
Repositório:Repositório Institucional da UNESP
Idioma:inglês
OAI Identifier:oai:repositorio.unesp.br:11449/190092
Acesso em linha:http://dx.doi.org/10.1590/0104-6632.20180353s20170098
http://hdl.handle.net/11449/190092
Access Level:Acceso aberto
Palavra-chave:Breakage
Flocculation
Image analysis
Descrição
Resumo:The reversibility of aggregates during flocculation was investigated. The stable diameter (d) and the power law slope coefficient of the particle size distribution (β) were applied to follow re-formation after breakage. A non-intrusive image-based technique was used for monitoring flocs. Aggregates were formed by adding alum [Al 2 (SO 4 ) 3 ·18H 2 O] by the sweep-coagulation mechanism to two synthetic waters, prepared from kaolin (Fluka) and humic acid (Aldrich Chemical). Velocity gradients (G) varied from 20 to 120 s -1 during experiments, and the rupture occurred under controlled conditions. After rupture, the initial condition was reinstated and reversibility analyzed. Results pointed out the irreversibility of breakage for both Al-kaolin and Al-humic flocs. The stable diameter of aggregates after breakage (d 2 ) varied from 157 to 132 µm for Al-humic and from 233 to 123µm for Al-kaolin aggregates, using G from 20 to 120 s -1 . β 2 values varied from 1.2 to 4.6 for Al-humic and from 0.6 to 7.7 for Al-kaolin.