Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel
Wild mustard (Brassica juncea L.) oil is evaluated as a feedstock for biodiesel production. Biodiesel was obtained in 94 wt.% yield by a standard transesterification procedure with methanol and sodium methoxide catalyst. Wild mustard oil had a high content of erucic (13(Z)‐docosenoic; 45.7 wt.%) aci...
| Autores: | , , , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2009 |
| País: | Brasil |
| Institución: | Universidade Federal de Viçosa (UFV) |
| Repositorio: | LOCUS Repositório Institucional da UFV |
| Idioma: | inglés |
| OAI Identifier: | oai:locus.ufv.br:123456789/22526 |
| Acceso en línea: | http://dx.doi.org/10.1007/s11746-009-1431-2 http://www.locus.ufv.br/handle/123456789/22526 |
| Access Level: | acceso abierto |
| Palabra clave: | Biodiesel Brassica juncea Fatty acid methyl esters Phytosterols Tocopherols Transesterification Wild mustard |
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Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuelBiodieselBrassica junceaFatty acid methyl estersPhytosterolsTocopherolsTransesterificationWild mustardWild mustard (Brassica juncea L.) oil is evaluated as a feedstock for biodiesel production. Biodiesel was obtained in 94 wt.% yield by a standard transesterification procedure with methanol and sodium methoxide catalyst. Wild mustard oil had a high content of erucic (13(Z)‐docosenoic; 45.7 wt.%) acid, with linoleic (9(Z),12(Z)‐octadecadienoic; 14.2 wt.%) and linolenic (9(Z),12(Z),15(Z)‐octadecatrienoic; 13.0 wt.%) acids comprising most of the remaining fatty acid profile. The cetane number, kinematic viscosity, and oxidative stability (Rancimat method) of the methyl esters was 61.1, 5.33 mm^2 s^−1 (40 °C) and 4.8 h (110 °C), respectively. The cloud, pour and cold filter plugging points were 4, −21 and −3 °C, respectively. Other properties such as acid value, lubricity, free and total glycerol content, iodine value, Gardner color, specific gravity, as well as sulfur and phosphorous contents were also determined and are discussed in light of biodiesel standards ASTM D6751 and EN 14214. Also reported are the properties and composition of wild mustard oil, along with identification of wild mustard collected in Brazil as Brassica juncea L. (2n = 36) as opposed to the currently accepted Sinapis arvensis L. (2n = 18) classification. In summary, wild mustard oil appears to be an acceptable feedstock for biodiesel production.Journal of the American Oil Chemists' Society2018-11-12T16:48:13Z2018-11-12T16:48:13Z2009-07-03info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlepdfapplication/pdf15589331http://dx.doi.org/10.1007/s11746-009-1431-2http://www.locus.ufv.br/handle/123456789/22526engv. 86, n. 9, p. 917– 926, set. 2009info:eu-repo/semantics/openAccessreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVJham, Gulab N.Moser, Bryan R.Shah, Shailesh N.Holser, Ronald A.Dhingra, Onkar D.Vaughn, Steven F.Berhow, Mark A.Winkler-Moser, Jill K.Isbell, Terry A.Holloway, Ray K.Walter, Erin L.Natalino, RicardoAnderson, Jason C.Stelly, David M.2024-07-12T06:55:54Zoai:locus.ufv.br:123456789/22526Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452024-07-12T06:55:54LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
| dc.title.none.fl_str_mv |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| title |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| spellingShingle |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel Jham, Gulab N. Biodiesel Brassica juncea Fatty acid methyl esters Phytosterols Tocopherols Transesterification Wild mustard |
| title_short |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| title_full |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| title_fullStr |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| title_full_unstemmed |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| title_sort |
Wild brazilian mustard (Brassica juncea L.) seed oil methyl esters as biodiesel fuel |
| dc.creator.none.fl_str_mv |
Jham, Gulab N. Moser, Bryan R. Shah, Shailesh N. Holser, Ronald A. Dhingra, Onkar D. Vaughn, Steven F. Berhow, Mark A. Winkler-Moser, Jill K. Isbell, Terry A. Holloway, Ray K. Walter, Erin L. Natalino, Ricardo Anderson, Jason C. Stelly, David M. |
| author |
Jham, Gulab N. |
| author_facet |
Jham, Gulab N. Moser, Bryan R. Shah, Shailesh N. Holser, Ronald A. Dhingra, Onkar D. Vaughn, Steven F. Berhow, Mark A. Winkler-Moser, Jill K. Isbell, Terry A. Holloway, Ray K. Walter, Erin L. Natalino, Ricardo Anderson, Jason C. Stelly, David M. |
| author_role |
author |
| author2 |
Moser, Bryan R. Shah, Shailesh N. Holser, Ronald A. Dhingra, Onkar D. Vaughn, Steven F. Berhow, Mark A. Winkler-Moser, Jill K. Isbell, Terry A. Holloway, Ray K. Walter, Erin L. Natalino, Ricardo Anderson, Jason C. Stelly, David M. |
| author2_role |
author author author author author author author author author author author author author |
| dc.subject.por.fl_str_mv |
Biodiesel Brassica juncea Fatty acid methyl esters Phytosterols Tocopherols Transesterification Wild mustard |
| topic |
Biodiesel Brassica juncea Fatty acid methyl esters Phytosterols Tocopherols Transesterification Wild mustard |
| description |
Wild mustard (Brassica juncea L.) oil is evaluated as a feedstock for biodiesel production. Biodiesel was obtained in 94 wt.% yield by a standard transesterification procedure with methanol and sodium methoxide catalyst. Wild mustard oil had a high content of erucic (13(Z)‐docosenoic; 45.7 wt.%) acid, with linoleic (9(Z),12(Z)‐octadecadienoic; 14.2 wt.%) and linolenic (9(Z),12(Z),15(Z)‐octadecatrienoic; 13.0 wt.%) acids comprising most of the remaining fatty acid profile. The cetane number, kinematic viscosity, and oxidative stability (Rancimat method) of the methyl esters was 61.1, 5.33 mm^2 s^−1 (40 °C) and 4.8 h (110 °C), respectively. The cloud, pour and cold filter plugging points were 4, −21 and −3 °C, respectively. Other properties such as acid value, lubricity, free and total glycerol content, iodine value, Gardner color, specific gravity, as well as sulfur and phosphorous contents were also determined and are discussed in light of biodiesel standards ASTM D6751 and EN 14214. Also reported are the properties and composition of wild mustard oil, along with identification of wild mustard collected in Brazil as Brassica juncea L. (2n = 36) as opposed to the currently accepted Sinapis arvensis L. (2n = 18) classification. In summary, wild mustard oil appears to be an acceptable feedstock for biodiesel production. |
| publishDate |
2009 |
| dc.date.none.fl_str_mv |
2009-07-03 2018-11-12T16:48:13Z 2018-11-12T16:48:13Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
15589331 http://dx.doi.org/10.1007/s11746-009-1431-2 http://www.locus.ufv.br/handle/123456789/22526 |
| identifier_str_mv |
15589331 |
| url |
http://dx.doi.org/10.1007/s11746-009-1431-2 http://www.locus.ufv.br/handle/123456789/22526 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
v. 86, n. 9, p. 917– 926, set. 2009 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
pdf application/pdf |
| dc.publisher.none.fl_str_mv |
Journal of the American Oil Chemists' Society |
| publisher.none.fl_str_mv |
Journal of the American Oil Chemists' Society |
| dc.source.none.fl_str_mv |
reponame:LOCUS Repositório Institucional da UFV instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
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Universidade Federal de Viçosa (UFV) |
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UFV |
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UFV |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV) |
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fabiojreis@ufv.br |
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15.300724 |