Imprint effect in PZT thin films at compositions around the morphotropic phase boundary

Piezoeresponse force microscopy (PFM) and local piezoresponse hysteresis loops were used to study the imprint effect in PbZr1-xTixO3 thin films at compositions around the morphotropic phase boundary (MPB). Schottky barriers and mechanical coupling between film-substrate were excluded as origin for t...

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Detalles Bibliográficos
Autores: Araujo, E. B. [UNESP], Lima, E. C., Bdikin, I. K., Kholkin, A. L.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/173097
Acceso en línea:http://dx.doi.org/10.1080/00150193.2016.1166421
http://hdl.handle.net/11449/173097
Access Level:acceso abierto
Palabra clave:Imprint
PZT
thin films
Descripción
Sumario:Piezoeresponse force microscopy (PFM) and local piezoresponse hysteresis loops were used to study the imprint effect in PbZr1-xTixO3 thin films at compositions around the morphotropic phase boundary (MPB). Schottky barriers and mechanical coupling between film-substrate were excluded as origin for the imprint in these films. Comparing the composition dependence of the effective d33 before poling with some reports in the literature, the existence of point defects such as complex vacancies (Vpb .., VO .. and Vpb ..-VO ..) and Ti3+ centers is discussed as probable origin for the imprint effect observed here.