Bending of Layer-by-Layer Films Driven by an External Magnetic Field

We report on optimized architectures containing layer-by-layer (LbL) films of natural rubber latex (NRL), carboxymethyl-chitosan (CMC) and magnetite (Fe3O4) nanoparticles (MNPs) deposited on flexible substrates, which could be easily bent by an external magnetic field. The mechanical response depend...

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Detalles Bibliográficos
Autores: Miyazaki, Celina M., Riul, Antonio, Dos Santos, David S., Ferreira, Mariselma, Constantino, Carlos J. L. [UNESP], Pereira-da-Silva, Marcelo A., Paupitz, Ricardo [UNESP], Galvao, Douglas S., Oliveira, Osvaldo N.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/113383
Acceso en línea:http://dx.doi.org/10.3390/ijms140712953
http://hdl.handle.net/11449/113383
Access Level:acceso abierto
Palabra clave:magnetic nanoparticles
natural rubber latex
carboxymethyl-chitosan
layer-by-layer assembly
molecular dynamics
Descripción
Sumario:We report on optimized architectures containing layer-by-layer (LbL) films of natural rubber latex (NRL), carboxymethyl-chitosan (CMC) and magnetite (Fe3O4) nanoparticles (MNPs) deposited on flexible substrates, which could be easily bent by an external magnetic field. The mechanical response depended on the number of deposited layers and was explained semi-quantitatively with a fully atomistic model, where the LbL film was represented as superposing layers of hexagonal graphene-like atomic arrangements deposited on a stiffer substrate. The bending with no direct current or voltage being applied to a supramolecular structure containing biocompatible and antimicrobial materials represents a proof-of-principle experiment that is promising for tissue engineering applications in biomedicine.