The Theoretical Description of Cathodic Deposition of New Conducting Polymer Composite, Assisted by a Perrhenate of a Novel Triazolic Derivative
The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerizatio...
| Autores: | , , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2020 |
| País: | Brasil |
| Institución: | Universidade Federal de Mato Grosso do Sul (UFMS) |
| Repositorio: | Orbital - The Electronic Journal of Chemistry (Campo Grande) |
| Idioma: | inglés |
| OAI Identifier: | oai:periodicos.ufms.br:article/15741 |
| Acceso en línea: | https://periodicos.ufms.br/index.php/orbital/article/view/15741 |
| Access Level: | acceso abierto |
| Palabra clave: | conducting polymer composites rhenium assisted polymerization electrochemical oscillations stable steady-state |
| Sumario: | The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerization. It is shown that the polymer deposition in this system is realized by more efficient manner than during the direct electropolymerization. The polymer composite has to have a well-developed morphology and enhanced conductivity by sandwich-like structure. The oscillatory behavior, in this case, is also possible, being caused by the DEL influences on both electrochemical and chemical stages of the process. DOI: http://dx.doi.org/10.17807/orbital.v12i2.1193 |
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