Study of castor oil polyurethane - poly (methyl methacrylate) semi-interpenetrating polymer network (SIPN) reaction parameters using a 2³ factorial experimental design
In this work was employed a 23 factorial experiment design to evaluate the castor oil polyurethane- poly(methyl methacrylate) semi-IPN synthesis. The reaction parameters used as independent variables were NCO/OH molar ratio, polyurethane polymerization time and methyl methacrylate (MMA) content. The...
| Authors: | , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2004 |
| Country: | Brasil |
| Institution: | Universidade Federal do Rio Grande do Sul (UFRGS) |
| Repository: | Repositório Institucional da UFRGS |
| Language: | English |
| OAI Identifier: | oai:www.lume.ufrgs.br:10183/19877 |
| Online Access: | http://hdl.handle.net/10183/19877 |
| Access Level: | Open access |
| Keyword: | Polímeros Castor oil Semi-IPN Experimental design Poly (methyl methacrylate) |
| Summary: | In this work was employed a 23 factorial experiment design to evaluate the castor oil polyurethane- poly(methyl methacrylate) semi-IPN synthesis. The reaction parameters used as independent variables were NCO/OH molar ratio, polyurethane polymerization time and methyl methacrylate (MMA) content. The semi-IPNs were cured over 28 h using two thermal treatments. The polymers were characterized by infrared and Raman spectroscopy, thermal analysis and swelling profiles in n-hexane. The glass transition temperature (Tg) and the swelling were more affect by the NCO/OH molar ratio variation. The semi-IPNs showed Tg from - 27 to - 6 °C and the swelling range was from 3 to 22%, according to the crosslink density. The IPN mechanical properties were dependent on the cure temperature and MMA content in it. Lower elastic modulus values were observed in IPNs cured at room temperature. |
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