Application of Amine-based Ru Compounds in the Olefin Metathesis of Methyl Eugenol: A Comparison with Grubbs Catalysts

Methyl eugenol olefin metathesis was conducted with non-carbene Ru-complexes ([RuCl2(PPh3)(2)amine]) in the absence and presence of SnCl2 or CuCl2 as additives and their catalytic activities were compared with that of a commercial Grubbs catalyst 2nd Generation (G2).

Detalhes bibliográficos
Autores: Sousa, Denise A., Meneses, Paulo S., Gois, Patrik D. S. [UNESP], Silva, Eliada A., Junior, Valdemiro P. C. [UNESP], Lima-Neto, Benedito S., Silva Sa, Jose L.
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2020
País:Brasil
Recursos:Universidade Estadual Paulista (UNESP)
Repositório:Repositório Institucional da UNESP
Idioma:inglês
OAI Identifier:oai:repositorio.unesp.br:11449/195613
Acesso em linha:http://dx.doi.org/10.2174/1570178617666191127102552
http://hdl.handle.net/11449/195613
Access Level:Acceso aberto
Palavra-chave:Olefin metathesis
Methyl-eugenol
SnCl2
CuCl2
ruthenium
additives
Descrição
Resumo:Methyl eugenol olefin metathesis was conducted with non-carbene Ru-complexes ([RuCl2(PPh3)(2)amine]) in the absence and presence of SnCl2 or CuCl2 as additives and their catalytic activities were compared with that of a commercial Grubbs catalyst 2nd Generation (G2).

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