The influence of soluble salts content on the performance of an epoxy coating system via accelerated corrosion tests

ABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of...

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Detalles Bibliográficos
Autores: Zimmermann,Camila Aparecida, Koslowski,Luciano André Deitos, Araújo,Maria Inês Siqueira, Silveira,Marcia Luciane Lange
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:Brasil
Institución:Matéria (Rio de Janeiro. Online)
Repositorio:Matéria (Rio de Janeiro. Online)
Idioma:inglés
OAI Identifier:oai:scielo:S1517-70762020000200340
Acceso en línea:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000200340
Access Level:acceso abierto
Palabra clave:Carbon steel
Corrosion
Soluble Salts Content
Epoxy
Paint
Descripción
Sumario:ABSTRACT It is generally accepted that surpassing a threshold value of water-soluble salts at the substrate/coating interface can impart premature failure in painted structures. The Coatings industry has an identified need in defining a maximum allowable soluble salts content, however, a variety of threshold values are found in published data. Based on that, this work aims at evaluate the effect on epoxy coating performance of three different ranges of soluble salts content taking into account the maximum allowable values specified by NORSOK M-501 and IMO PSPC MSC.215, two important standards of naval and offshore sectors. Blast-cleaned carbon steel specimens contaminated with sodium chloride solutions diluted in methanol ranging 20, 50 and 100 mg/m² NaCl were painted with two epoxy-amine paint coats. Samples were evaluated by cathodic disbondment, water immersion at 40 ºC, pull-off adhesion strength and cyclic corrosion tests. Larger blisters and loss of adhesion were observed as the soluble salts content at the interface increased. Although, it was not possible to find a critical level of soluble salts even considering data about similar coating systems. A safe soluble salt content must be chosen based on tests that closer reproduce service and environmental conditions to which a painted structure will be exposed.