Biomass ashes to produce an alternative alkaline activator for alkali-activated cements

In the last decade, herbaceous and agricultural biomass have been used as an alternative energy source. As consequence, large amounts of residual ashes containing potassium (potassium-rich ashes) have been generated. Olive biomass ash (OBA) and almond shell ash (ABA) have been successfully used as a...

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Detalles Bibliográficos
Autores: Soriano, L., Font, A., Borrachero, M. V., Monzó, J. M., Payá, J., Tashima, M. M. [UNESP]
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/222862
Acceso en línea:http://dx.doi.org/10.1016/j.matlet.2021.131198
http://hdl.handle.net/11449/222862
Access Level:acceso abierto
Palabra clave:Alkali-activated cement
Biomass ash
Blast furnace slag
Chemical composition
High potassium ashes
Valorisation
Descripción
Sumario:In the last decade, herbaceous and agricultural biomass have been used as an alternative energy source. As consequence, large amounts of residual ashes containing potassium (potassium-rich ashes) have been generated. Olive biomass ash (OBA) and almond shell ash (ABA) have been successfully used as alkali source in the alkaline activation of ground granulated blast furnace slag (BFS). This study focuses on the production of new and alternative alkaline activators for BFS systems using nutshell ashes (NBA), mango seed-bark ashes (MBA) and hazelnut shell ashes (HBA). The chemical and mineralogical composition of these ashes were assessed and, the mechanical and microstructural properties of BFS pastes activated with NBA, MBA and HBA were evaluated. The results indicated that all assessed materials are potassium-rich ashes differing mainly on the amount of CaO and P2O5. The compressive strength of BFS pastes yielded about 26 MPa and, according to FESEM/EDS analysis, K2O (in the range 8.03–24.33%) replaces chemical bounded Ca+2, forming C-(K)-A-S-H gel.