Sulfur and zinc availability from co-granulated Zn-enriched elemental sulfur fertilizers

Acidification by oxidation of elemental sulfur (ES) can solubilize ZnO, providing slow release of both sulfur (S) and zinc (Zn) in soil. For this study, a new granular fertilizer with ES and ZnO was produced and evaluated. The effect of incorporating microorganisms or a carbon source in the granule...

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Detalles Bibliográficos
Autores: Mattiello, Edson M., Silva, Rodrigo C. da, Degryse, Fien, Baird, Roslyn, Gupta, Vadakattu V. S. R., McLaughlin, Michael J.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:Brasil
Institución:Universidade Federal de Viçosa (UFV)
Repositorio:LOCUS Repositório Institucional da UFV
Idioma:inglés
OAI Identifier:oai:locus.ufv.br:123456789/19440
Acceso en línea:http://dx.doi.org/10.1021/acs.jafc.6b04586
http://www.locus.ufv.br/handle/123456789/19440
Access Level:acceso abierto
Palabra clave:Acidithiobacillus thiooxidans
Aspergillus niger
Micronutrients
Sulfur oxidation
Zn diffusion
ZnO
Descripción
Sumario:Acidification by oxidation of elemental sulfur (ES) can solubilize ZnO, providing slow release of both sulfur (S) and zinc (Zn) in soil. For this study, a new granular fertilizer with ES and ZnO was produced and evaluated. The effect of incorporating microorganisms or a carbon source in the granule was also evaluated. Four granulated ES–Zn fertilizers with and without S-oxidizing microorganisms, a commercial ES pastille, ZnSO4, and ZnO were applied to the center of Petri dishes containing two contrasting pH soils. Soil pH, CaCl2-extractable S and Zn, and remaining ES were evaluated at 30 and 60 days in two soil sections (0–5 and 5–9 mm from the fertilizer application site). A visualization test was performed to evaluate Zn diffusion over time. A significant pH decrease was observed in the acidic soil for all ES–Zn fertilizer treatments and in the alkaline soil for the Acidithiobacillus thiooxidans-inoculated treatment only. In agreement with Zn visualization tests, extractable-Zn concentrations were higher from the point of application in the acidic (62.9 mg dm–3) compared to the alkaline soil (5.5 mg dm–3). Elemental S oxidation was greater in the acidic soil (20.9%) than slightly alkaline soil (12%). The ES–Zn granular fertilizers increased S and Zn concentrations in soil and can provide a strategically slow release of nutrients to the soil.