Estudo ab initio do sistema molecular HCO de interesse atmosférico.

In this work high-level ab initio calculations have been performed using CASSCF determinants for a MRCI function and an ACV5Z-DK basis, jointly with a preliminary fit of a potential energy function to those points. Until the date of the defence of this dissertation it was possible to carry out a stu...

Descripción completa

Detalles Bibliográficos
Autor: Coura, Daniel Vitor Barbosa
Tipo de recurso: tesis de maestría
Estado:Versión publicada
Fecha de publicación:2018
País:Brasil
Institución:Universidade Federal do Espírito Santo (UFES)
Repositorio:Repositório Institucional da Universidade Federal do Espírito Santo (riUfes)
Idioma:portugués
OAI Identifier:oai:repositorio.ufes.br:10/7371
Acceso en línea:http://repositorio.ufes.br/handle/10/7371
Access Level:acceso abierto
Palabra clave:Molecular interaction
Ab initio calculations
Interação molecular
Cálculos ab initio
Molécula HCO
Física
Descripción
Sumario:In this work high-level ab initio calculations have been performed using CASSCF determinants for a MRCI function and an ACV5Z-DK basis, jointly with a preliminary fit of a potential energy function to those points. Until the date of the defence of this dissertation it was possible to carry out a study of the global minimum of the potential energy surface of HCO, some local minimum and some transition states. The main objective of the work we have here started is the construction of a global potential energy surface for the ground state of the HCO molecule.