Effect of soy protein isolate on the thermal, mechanical and morphological properties of poly (ε-caprolactone) and corn starch blends

The development of biodegradable polymers is considered to be a good alternative to decrease the volume of the plastic waste disposed into the environment every year. The use of natural polymers as raw materials to develop polymer blends and composites has increased the demand for renewable sources...

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Detalles Bibliográficos
Autores: Mariani, P. D.S.C., Allganer, K., Oliveira, F. B., Cardoso, E. J.B.N. [UNESP], Innocentini-Mei, L. H.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2009
País:Brasil
Institución:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/219523
Acceso en línea:http://dx.doi.org/10.1016/j.polymertesting.2009.07.004
http://hdl.handle.net/11449/219523
Access Level:acceso abierto
Palabra clave:Characterization
Poly(ε-caprolactone)
Soy protein
Starch
Descripción
Sumario:The development of biodegradable polymers is considered to be a good alternative to decrease the volume of the plastic waste disposed into the environment every year. The use of natural polymers as raw materials to develop polymer blends and composites has increased the demand for renewable sources such as starch and soy protein. In this work, the authors prepared and characterized the thermal, mechanical and morphological properties of blends based on poly (ε-caprolactone) and modified corn starch, with added soy protein isolate (SPI) and sorbitol. All samples were processed by extrusion in a single-screw extruder and hot pressing. It was observed that the addition of modified corn starch and SPI were responsible for the reduction of thermal and mechanical properties of the materials, compared to pristine PCL. However, with increasing amounts of SPI and the reduction of starch incorporated into the samples, their properties tend to recover. The insertion of soy protein isolate in the formulations was done with the aim of balancing the C/N ratio of the blend, which plays a key role in the biodegradation process of these materials. © 2009 Elsevier Ltd. All rights reserved.