2,2'-Bipyridine Equipped with a Disulfide/Dithiol Switch for Coupled Two Electron and Proton Transfer
[1,2]dithiino[4,3-b:5,6-b´]dipyridine (1) and its protonated open form 3,3´-dithiol-2,2´-bipyridine (2) were synthesised and their interconversion investigated. The X-ray structure of 2 revealed an anti orientation of the two pyridine units and a zwitterionic form. In depth electrochemical studies i...
| Authors: | , , , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2018 |
| Country: | Argentina |
| Institution: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repository: | CONICET Digital (CONICET) |
| Language: | English |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/85505 |
| Online Access: | http://hdl.handle.net/11336/85505 |
| Access Level: | Open access |
| Keyword: | disulfide bipyridine ligands multiredox https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Summary: | [1,2]dithiino[4,3-b:5,6-b´]dipyridine (1) and its protonated open form 3,3´-dithiol-2,2´-bipyridine (2) were synthesised and their interconversion investigated. The X-ray structure of 2 revealed an anti orientation of the two pyridine units and a zwitterionic form. In depth electrochemical studies in combination with DFT calculations lead to a comprehensive picture of the redox chemistry of 1 in the absence and presence of protons. Initial one electron reduction at E1 = −1.97 V results in the formation of the radical anion 1red with much elongated S-S bond, which readily undergoes further reduction at E2 = −2.15 V. Water triggers a potential inversion (E ≥ −1.9 V for the second reduction) as the radical anion 1red is protonated at its basic N atom. DFT studies revealed that S−S bond breaking and twisting of the pyridine units generally occurs after the second reduction step while the potential inversion induced by protonation is a result of charge compensation. The CV data were simulated to derive rate constants for the individual chemical and electrochemical reactions for both scenarios in the absence and presence of protons. |
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