Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene
Ablated, “pseudo-naked” gold nanoparticles (AuNPs) catalyze the cis–trans isomerization of substituted azobenzenes. para-Substitution was found to affect the rate of isomerization, suggesting the participation of AuNP-mediated electron transfer in the isomerization mechanism.
| Authors: | , , , , , , , |
|---|---|
| Format: | article |
| Status: | Published version |
| Publication Date: | 2013 |
| Country: | Argentina |
| Institution: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repository: | CONICET Digital (CONICET) |
| Language: | English |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/25997 |
| Online Access: | http://hdl.handle.net/11336/25997 |
| Access Level: | Open access |
| Keyword: | Azobenzenes Nanocatalysis Isomerization Gold https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
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Gold nanoparticle catalysis of the cis-trans isomerization of azobenzeneHallet Tapley, GenieceD'Alfonso, ClaudioPacioni, Natalia LorenaMcTiernan, Cristopher D.Gonzalez Bejar, MariaLanzalunga, OsvaldoAlarcon, Emilio I.Scaiano, Juan CesarAzobenzenesNanocatalysisIsomerizationGoldhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Ablated, “pseudo-naked” gold nanoparticles (AuNPs) catalyze the cis–trans isomerization of substituted azobenzenes. para-Substitution was found to affect the rate of isomerization, suggesting the participation of AuNP-mediated electron transfer in the isomerization mechanism.Fil: Hallet Tapley, Geniece. University of Ottawa; CanadáFil: D'Alfonso, Claudio. University of Ottawa; Canadá. Universita Di Roma; ItaliaFil: Pacioni, Natalia Lorena. University of Ottawa; CanadáFil: McTiernan, Cristopher D.. University of Ottawa; CanadáFil: Gonzalez Bejar, Maria. University of Ottawa; Canadá. Universidad de Valencia; EspañaFil: Lanzalunga, Osvaldo. Universita Di Roma; ItaliaFil: Alarcon, Emilio I.. University of Ottawa; CanadáFil: Scaiano, Juan Cesar. University of Ottawa; Canadá. Universidad de Valencia; EspañaRoyal Society of Chemistry2013-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25997Hallet Tapley, Geniece; D'Alfonso, Claudio; Pacioni, Natalia Lorena; McTiernan, Cristopher D.; Gonzalez Bejar, Maria; et al.; Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene; Royal Society of Chemistry; Chemical Communications; 49; 86; 8-2013; 10073-100751359-7345CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c3cc41669kinfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc41669k#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:48:52Zoai:ri.conicet.gov.ar:11336/25997instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:48:52.345CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| title |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| spellingShingle |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene Hallet Tapley, Geniece Azobenzenes Nanocatalysis Isomerization Gold https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| title_short |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| title_full |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| title_fullStr |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| title_full_unstemmed |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| title_sort |
Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene |
| dc.creator.none.fl_str_mv |
Hallet Tapley, Geniece D'Alfonso, Claudio Pacioni, Natalia Lorena McTiernan, Cristopher D. Gonzalez Bejar, Maria Lanzalunga, Osvaldo Alarcon, Emilio I. Scaiano, Juan Cesar |
| author |
Hallet Tapley, Geniece |
| author_facet |
Hallet Tapley, Geniece D'Alfonso, Claudio Pacioni, Natalia Lorena McTiernan, Cristopher D. Gonzalez Bejar, Maria Lanzalunga, Osvaldo Alarcon, Emilio I. Scaiano, Juan Cesar |
| author_role |
author |
| author2 |
D'Alfonso, Claudio Pacioni, Natalia Lorena McTiernan, Cristopher D. Gonzalez Bejar, Maria Lanzalunga, Osvaldo Alarcon, Emilio I. Scaiano, Juan Cesar |
| author2_role |
author author author author author author author |
| dc.subject.none.fl_str_mv |
Azobenzenes Nanocatalysis Isomerization Gold https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| topic |
Azobenzenes Nanocatalysis Isomerization Gold https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| description |
Ablated, “pseudo-naked” gold nanoparticles (AuNPs) catalyze the cis–trans isomerization of substituted azobenzenes. para-Substitution was found to affect the rate of isomerization, suggesting the participation of AuNP-mediated electron transfer in the isomerization mechanism. |
| publishDate |
2013 |
| dc.date.none.fl_str_mv |
2013-08 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/25997 Hallet Tapley, Geniece; D'Alfonso, Claudio; Pacioni, Natalia Lorena; McTiernan, Cristopher D.; Gonzalez Bejar, Maria; et al.; Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene; Royal Society of Chemistry; Chemical Communications; 49; 86; 8-2013; 10073-10075 1359-7345 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/25997 |
| identifier_str_mv |
Hallet Tapley, Geniece; D'Alfonso, Claudio; Pacioni, Natalia Lorena; McTiernan, Cristopher D.; Gonzalez Bejar, Maria; et al.; Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene; Royal Society of Chemistry; Chemical Communications; 49; 86; 8-2013; 10073-10075 1359-7345 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1039/c3cc41669k info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc41669k#!divAbstract |
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info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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openAccess |
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
| dc.format.none.fl_str_mv |
application/pdf application/pdf |
| dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
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Royal Society of Chemistry |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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15,81155 |