Ageing effects in Ag-Ge-Se bulk glasses

Glasses of composition Agx(Ge0.25Se0.75)100-xand Agx(Ge0.25Se0.75)100-xdoped with 0.5 at% of 57Fe were analyzed with the aim to evaluate if their structure evidences any effect of ageing, for thousands of hours at room temperature and/or hundreds of hours for sub-Tg thermal treatments. Strong ageing...

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Detalles Bibliográficos
Autores: Pérez, P. Gimena, Conde Garrido, Juan Manuel, Soria, Delia Beatriz, Ureña, María Andrea, Fontana, Marcelo, Arcondo, Bibiana
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/95999
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/95999
Access Level:acceso abierto
Palabra clave:Ingeniería Química
Chalcogenide glasses
Ag-Ge-Se
Relaxation effects
Raman spectroscopy
Descripción
Sumario:Glasses of composition Agx(Ge0.25Se0.75)100-xand Agx(Ge0.25Se0.75)100-xdoped with 0.5 at% of 57Fe were analyzed with the aim to evaluate if their structure evidences any effect of ageing, for thousands of hours at room temperature and/or hundreds of hours for sub-Tg thermal treatments. Strong ageing effects were observed by means of Mössbauer spectroscopywhereas Raman spectroscopy contributed to identify the origin of these effects.