Brass dezincification in a tap water bacterial suspension

The dezincification of Al-brass under the influence of Pseudomona fluorescens in potable water is investigated. The experiments were carried out using artificial tap water, pH 7.6. For comparison, a bacterial suspension, was also used. Potentiodynamic reduction curves, polarization curves, polarizat...

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Detalles Bibliográficos
Autores: Valcarce, María Beatriz, Rosso de Sanchez, Maria Susana, Vazquez, Marcela Vivian
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2006
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/70781
Acceso en línea:http://hdl.handle.net/11336/70781
Access Level:acceso abierto
Palabra clave:Copper Alloy
Corrosion
Dealloying
Electrochemistry
Optical Reflectivity
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descripción
Sumario:The dezincification of Al-brass under the influence of Pseudomona fluorescens in potable water is investigated. The experiments were carried out using artificial tap water, pH 7.6. For comparison, a bacterial suspension, was also used. Potentiodynamic reduction curves, polarization curves, polarization resistance and impedance spectroscopy as well as reflectance spectroscopy were used to characterise the surface films grown at open circuit potential. The dezincification associated to the presence of bacteria was revealed by changes in the reduction curves, and also by changes in the reflectance spectra. No significant differences were observed between the fitting parameters of the impedance spectra. The Tafel slopes were found to increase in the bacterial suspension. The corrosion currents are higher than in the inoculated electrolyte, particularly in the case of brass. This increment is attributed to the higher Tafel slope and is taken as an indication of the dezincification phenomenon. © 2005 Elsevier Ltd. All rights reserved.