Electrodeposition of polypyrrole on Nitinol alloy in the presence of inhibitor ions for corrosion protection

The electrosynthesis of polypyrrole (PPy) films on Nitinol (NiTi) from solutions containing different corrosion inhibitors is reported. The corrosion behaviour of the coated samples was investigated in 0.15 M NaCl solution. The presence of molybdate ions in the polymer matrix confers to the substrat...

Descripción completa

Detalles Bibliográficos
Autores: Flamini, Daniel Omar, Saugo, Melisa, Saidman, Silvana Beatriz
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/21713
Acceso en línea:http://hdl.handle.net/11336/21713
Access Level:acceso abierto
Palabra clave:Nickel
Titanium
Eis
Electrodeposited Films
Pitting Corrosion
Polymer Coatings
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
Descripción
Sumario:The electrosynthesis of polypyrrole (PPy) films on Nitinol (NiTi) from solutions containing different corrosion inhibitors is reported. The corrosion behaviour of the coated samples was investigated in 0.15 M NaCl solution. The presence of molybdate ions in the polymer matrix confers to the substrate a greater resistance to pitting corrosion. The polymer formed potentiostatically in a solution at pH 12 containing nitrate and molybdate is the most efficient in terms of adhesion and corrosion protection. Results are interpreted in terms of the nature of the dopants, the good electroactivity of the polymer and passive properties of the oxide layer.