Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content

Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based catalysts supported on silica were synthesized by inc...

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Autores: Faroldi, Betina María Cecilia, Paviotti, María Aneley, Camino-Manjarrés, M., González-Carrazán, S., López-Olmos, C., Rodríguez-Ramos, I.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/107897
Acceso en línea:http://hdl.handle.net/11336/107897
Access Level:acceso abierto
Palabra clave:HYDROGEN PRODUCTION
FORMIC ACID DECOMPOSITION
NICKEL CATALYST
CALCIUM OXIDE PROMOTER
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
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spelling Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium ContentFaroldi, Betina María CeciliaPaviotti, María AneleyCamino-Manjarrés, M.González-Carrazán, S.López-Olmos, C.Rodríguez-Ramos, I.HYDROGEN PRODUCTIONFORMIC ACID DECOMPOSITIONNICKEL CATALYSTCALCIUM OXIDE PROMOTERhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based catalysts supported on silica were synthesized by incipient wet impregnation. The eect of doping with an alkaline earth metal (calcium) wasstudied, and the solids were tested in the formic acid decomposition reaction to produce hydrogen.The catalysts were characterized by X-ray diraction (XRD), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and programmed temperature surface reaction (TPSR).The catalyst doped with 19.3 wt.% of Ca showed 100% conversion of formic acid at 160 C, with a 92% of selectivity to hydrogen. In addition, all the tested materials were promising for their application, since they showed catalytic behaviors (conversion and selectivity to hydrogen) comparable to thoseof noble metals reported in the literature.Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Paviotti, María Aneley. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Camino-Manjarrés, M.. Universidad de Salamanca; EspañaFil: González-Carrazán, S.. Universidad de Salamanca; EspañaFil: López-Olmos, C.. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaFil: Rodríguez-Ramos, I.. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaMDPI2019-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/107897Faroldi, Betina María Cecilia; Paviotti, María Aneley; Camino-Manjarrés, M.; González-Carrazán, S.; López-Olmos, C.; et al.; Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content; MDPI; Nanomaterials; 9; 11; 10-2019; 1-142079-4991CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2079-4991/9/11/1516info:eu-repo/semantics/altIdentifier/doi/10.3390/nano9111516info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:32:48Zoai:ri.conicet.gov.ar:11336/107897instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:32:49.072CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
title Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
spellingShingle Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
Faroldi, Betina María Cecilia
HYDROGEN PRODUCTION
FORMIC ACID DECOMPOSITION
NICKEL CATALYST
CALCIUM OXIDE PROMOTER
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
title_short Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
title_full Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
title_fullStr Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
title_full_unstemmed Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
title_sort Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content
dc.creator.none.fl_str_mv Faroldi, Betina María Cecilia
Paviotti, María Aneley
Camino-Manjarrés, M.
González-Carrazán, S.
López-Olmos, C.
Rodríguez-Ramos, I.
author Faroldi, Betina María Cecilia
author_facet Faroldi, Betina María Cecilia
Paviotti, María Aneley
Camino-Manjarrés, M.
González-Carrazán, S.
López-Olmos, C.
Rodríguez-Ramos, I.
author_role author
author2 Paviotti, María Aneley
Camino-Manjarrés, M.
González-Carrazán, S.
López-Olmos, C.
Rodríguez-Ramos, I.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv HYDROGEN PRODUCTION
FORMIC ACID DECOMPOSITION
NICKEL CATALYST
CALCIUM OXIDE PROMOTER
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
topic HYDROGEN PRODUCTION
FORMIC ACID DECOMPOSITION
NICKEL CATALYST
CALCIUM OXIDE PROMOTER
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
description Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based catalysts supported on silica were synthesized by incipient wet impregnation. The eect of doping with an alkaline earth metal (calcium) wasstudied, and the solids were tested in the formic acid decomposition reaction to produce hydrogen.The catalysts were characterized by X-ray diraction (XRD), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and programmed temperature surface reaction (TPSR).The catalyst doped with 19.3 wt.% of Ca showed 100% conversion of formic acid at 160 C, with a 92% of selectivity to hydrogen. In addition, all the tested materials were promising for their application, since they showed catalytic behaviors (conversion and selectivity to hydrogen) comparable to thoseof noble metals reported in the literature.
publishDate 2019
dc.date.none.fl_str_mv 2019-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/107897
Faroldi, Betina María Cecilia; Paviotti, María Aneley; Camino-Manjarrés, M.; González-Carrazán, S.; López-Olmos, C.; et al.; Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content; MDPI; Nanomaterials; 9; 11; 10-2019; 1-14
2079-4991
CONICET Digital
CONICET
url http://hdl.handle.net/11336/107897
identifier_str_mv Faroldi, Betina María Cecilia; Paviotti, María Aneley; Camino-Manjarrés, M.; González-Carrazán, S.; López-Olmos, C.; et al.; Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content; MDPI; Nanomaterials; 9; 11; 10-2019; 1-14
2079-4991
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2079-4991/9/11/1516
info:eu-repo/semantics/altIdentifier/doi/10.3390/nano9111516
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15,811543

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