Behavior of thiosemicarbazones derived from some terpenones under acetylation conditions. Part II

Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural α,β-unsaturated and bicyclic terpenones is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis. ©ARKAT.

Bibliographic Details
Authors: Rouge, P.D., Brousse, B.N., Moglioni, A.G., Cozzi, G.A., Alvarez-Larena, A., D'Accorso, N., Moltrasio, G.Y.
Format: article
Status:Published version
Publication Date:2005
Country:Argentina
Institution:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
Repository:Biblioteca Digital (UBA-FCEN)
Language:English
OAI Identifier:paperaa:paper_14246376_v2005_n12_p8_Rouge
Online Access:http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p8_Rouge
Access Level:Open access
Keyword:Spiro-nitrogenheterocycles
Spiro-sulphur heterocycles
Terpenoids
Thiadiazolines
Thiosemicarbazones
Description
Summary:Preparation of chiral heterocyclic compounds of the thiadiazoline types, starting from natural α,β-unsaturated and bicyclic terpenones is described. Stereochemical assignment of the compounds synthesized was performed by NMR spectroscopy and X-ray analysis. ©ARKAT.