Modelling of phenolic resin polymerisation

The kinetics of the polymerisation of resol-type phenolic resins has been modelled taking into account the phenol and formaldehyde equilibria. The kinetic parameters were obtained by adjusting the experimental evolution of phenol, formaldehyde and initial addition products during synthesis. The infl...

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Detalles Bibliográficos
Autores: Riccardi, Carmen Cristina, Astarloa Aierbe, G., Echeverría, J. M., Mondragon, I.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2002
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/37920
Acceso en línea:http://hdl.handle.net/11336/37920
Access Level:acceso abierto
Palabra clave:Kinetics
Modelling
Phenolic Resin
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
Descripción
Sumario:The kinetics of the polymerisation of resol-type phenolic resins has been modelled taking into account the phenol and formaldehyde equilibria. The kinetic parameters were obtained by adjusting the experimental evolution of phenol, formaldehyde and initial addition products during synthesis. The influence of the type and amount of catalyst, the initial pH, the initial formaldehyde-to-phenol molar ratio and the condensation temperature, on the kinetics rate constants was quantified.