Differential equation of a fractal electrode?electrolyte interface

Understanding an electrode-electrolyte interface (EEI) behavior is a valuable tool in several areas of science. There are models based on discrete fractal structures, which explain the measurements of linear and non-linear impedance at fixed frequencies, or at determined ranges of high and low curre...

Descripción completa

Detalles Bibliográficos
Autores: Felice, Carmelo Jose, Ruiz, Gabriel Alfredo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/184306
Acceso en línea:http://hdl.handle.net/11336/184306
Access Level:acceso abierto
Palabra clave:DIFFERENTIAL
ELECTROCHEMISTRY
ELECTRODES
FRACTAL
IMPEDANCE
https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
Descripción
Sumario:Understanding an electrode-electrolyte interface (EEI) behavior is a valuable tool in several areas of science. There are models based on discrete fractal structures, which explain the measurements of linear and non-linear impedance at fixed frequencies, or at determined ranges of high and low current densities. A level by level discrete calculation is needed to evaluate these models, or the use of black-box models, which affect the good understanding of the phenomenon. A continuous model based on a differential equation of an EEI is presented in this paper. It includes an electrical circuit similar to a long transmission line. It has been deduced from the discrete Liu model.