Phase transformations in Mo-doped FINEMETs

In this paper, the phase transformations occurring during the crystallization process of FINEMETs in which Nb has been gradually replaced by Mo have been studied by a variety of techniques including DSC, DTA, TGA, XRD and TEM. The thermal stability of the alloy was deteriorated as a consequence of M...

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Detalles Bibliográficos
Autores: Silveyra, Josefina María, Illeková, Emília, Švec, Peter, Janičkovič, Dušan, Rosales Rivera, Andrés, Cremaschi, Victoria Juliana
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2010
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/14824
Acceso en línea:http://hdl.handle.net/11336/14824
Access Level:acceso abierto
Palabra clave:Phase Transformations in Amorphous Alloys
Soft Magnetic Materials
Finemet
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Descripción
Sumario:In this paper, the phase transformations occurring during the crystallization process of FINEMETs in which Nb has been gradually replaced by Mo have been studied by a variety of techniques including DSC, DTA, TGA, XRD and TEM. The thermal stability of the alloy was deteriorated as a consequence of Mo’s smaller atomic size. The gradual replacement of Nb by Mo reduced the onset temperature of Fe–Si and of the borides. The Curie temperature of the amorphous phase slightly decreased from 594 K for x=0 to 587 K for x=3. The borides compounds Fe2B and Fe23B6 as well as the (Nb,Mo)5Si3 phase were found to precipitate in the second and third crystallization.