Vanadium-substituted keggin type heteropolyacid are used for the selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide
Various types of aromatic and aliphatic sulfides are selectively oxidized to sulfoxides and sulfones with good to excellent yields using H2O2 35% p/V in the presence of catalytic amounts of Keggin heteropolyacid (H5PMo11Al0.5O40) using acetonitrile as solvent.
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2007 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/54147 |
| Acceso en línea: | http://hdl.handle.net/11336/54147 |
| Access Level: | acceso abierto |
| Palabra clave: | Hydrogen Peroxide Keggin Heteropolyacid Oxidation Sulfides Sulfones Sulfoxides https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | Various types of aromatic and aliphatic sulfides are selectively oxidized to sulfoxides and sulfones with good to excellent yields using H2O2 35% p/V in the presence of catalytic amounts of Keggin heteropolyacid (H5PMo11Al0.5O40) using acetonitrile as solvent. |
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