Fenton oxidation as a strategy to preserve the biomass in the activated sludge system

Wastewaters containing biocides constitute an increasing environmental pollution concern. In this work, the feasibility of implementing a pretreatment based on the Fenton process to minimize the negative impact of biocide compounds, such asbenzalkonium chlorides (BAC), on the activated sludge system...

Full description

Bibliographic Details
Authors: Doumic, Lucila Inés, Almeida, Maria Esperanza, Giullietti, Giuliana, Ayude, María Alejandra, Ferro Orozco, Ana Micaela
Format: article
Status:Published version
Publication Date:2020
Country:Argentina
Institution:Consejo Nacional de Investigaciones Científicas y Técnicas
Repository:CONICET Digital (CONICET)
Language:English
OAI Identifier:oai:ri.conicet.gov.ar:11336/137980
Online Access:http://hdl.handle.net/11336/137980
Access Level:Open access
Keyword:Benzalconium chlorides
Fenton oxidation
Iron sludge
Activated sludge
Respirometric tests
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Description
Summary:Wastewaters containing biocides constitute an increasing environmental pollution concern. In this work, the feasibility of implementing a pretreatment based on the Fenton process to minimize the negative impact of biocide compounds, such asbenzalkonium chlorides (BAC), on the activated sludge system was studied. The behavior of the microbial community in the presence of a BAC solution untreated (BAC100) or pre-treated by homogeneous Fenton oxidation (BAC100/HF) was analyzed. The addition of BAC100 to the activated sludge system caused adeleterious effect. The cellular lysis process caused a 30% decrease in biomass concentration. The inhibition of respiratory activity was 73%. In contrast,BAC100/HF caused no significant decrease in the biomass concentration or detectable inhibition of the respiratory activity. Besides, the consumption of easily oxidizable products was observed. Results indicated that the homogeneous Fenton process as a pre-treatment of wastewaters containing BAC could become afeasible alternative to protect active biomass in biological treatment systems.