Photoinduced electron-transfer cycloreversion of thietanes: The role of ion-molecule complexes
Cycloreversion (CR) of thietane radical cations leads to formation of thiobenzophenone and the corresponding alkenes, eventually followed by secondary [4 + 2] cycloaddition. Final product distribution depends on the ability of fragments to escape from ion-molecule complexes (IMCs).
| Authors: | , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2010 |
| Country: | Argentina |
| Institution: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repository: | CONICET Digital (CONICET) |
| Language: | English |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/70441 |
| Online Access: | http://hdl.handle.net/11336/70441 |
| Access Level: | Open access |
| Keyword: | Electron Transfer Photochemistry Thietanes https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Summary: | Cycloreversion (CR) of thietane radical cations leads to formation of thiobenzophenone and the corresponding alkenes, eventually followed by secondary [4 + 2] cycloaddition. Final product distribution depends on the ability of fragments to escape from ion-molecule complexes (IMCs). |
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