Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates

We present a simple approach that avoids the problem of coupling fluid-sample interaction in confocal Raman depth-profiling with immersion objectives. We use a thin protective medium (polyethylene film) that preserves the sample from direct contact with the coupling fluid, and that can be readily at...

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Detalles Bibliográficos
Autores: Tomba, Juan Pablo, Pastor, José M.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2009
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/66218
Acceso en línea:http://hdl.handle.net/11336/66218
Access Level:acceso abierto
Palabra clave:Confocal Raman
Depth Profiling
Polymer Films
Immersion Objectives
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
Descripción
Sumario:We present a simple approach that avoids the problem of coupling fluid-sample interaction in confocal Raman depth-profiling with immersion objectives. We use a thin protective medium (polyethylene film) that preserves the sample from direct contact with the coupling fluid, and that can be readily attached/de-attached from the sample surface by applying a small difference of pressure. The strategy was tested performing confocal Raman depth profiling studies on a series of transparent substrates (polypropylene films; 25, 44 and 60 m nominal thickness) and comparing the results with those obtained with conventional approaches. It is shown that the strategy recovers very well all the film features, preserving at the same time a good depth resolution and optical throughput.