Schottky barriers measurements through Arrhenius plots in gas sensors based on semiconductor films

The oxygen adsorption effects on the Schottky barriers height measurements for thick films gas sensors prepared with undoped nanometric SnO2 particles were studied. From electrical measurements, the characteristics of the intergranular potential barriers developed at intergrains were deduced. It is...

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Detalles Bibliográficos
Autores: Schipani, Federico, Aldao, Celso Manuel, Ponce, Miguel Adolfo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2012
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/10741
Acceso en línea:http://hdl.handle.net/11336/10741
Access Level:acceso abierto
Palabra clave:SEMICONDUCTOR FILMS
SCHOTTKY BARRIERS
GAS SENSORS
TUNNELING
ACTIVATION ENERGIES
ATMOSPHERIC TEMPERATURE
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Descripción
Sumario:The oxygen adsorption effects on the Schottky barriers height measurements for thick films gas sensors prepared with undoped nanometric SnO2 particles were studied. From electrical measurements, the characteristics of the intergranular potential barriers developed at intergrains were deduced. It is shown that the determination of effective activation energies from conduction vs. 1/temperature curves is not generally a correct manner to estimate barrier heights. This is due to gas adsorption/desorption during the heating and cooling processes, the assumption of emission over the barrier as the dominant conduction mechanism, and the possible oxygen diffusion into or out of the grains.