The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]

The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordinat...

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Detalhes bibliográficos
Autores: Baggio, R., Garland, M.T., Perec, M.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:1996
País:Argentina
Recursos:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
Repositorio:Biblioteca Digital (UBA-FCEN)
Idioma:inglés
OAI Identifier:paperaa:paper_01082701_v52_n4_p823_Baggio
Acesso em linha:http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
Access Level:acceso abierto
Palavra-chave:Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
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network_acronym_str AR
network_name_str Argentina
repository_id_str
spelling The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]Baggio, R.Garland, M.T.Perec, M.Bromine compoundsCadmium compoundsChlorine compoundsCrystal atomic structureMolecular structureSpectroscopic analysisCadmium halide bis(diethyldithiocarbamate) complexesIsomorphous compoundsMononuclear complexesOrganometallicsThe title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively.Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.1996info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_BaggioActa Crystallogr Sect C Cryst Struct Commun 1996;52(4):823-826reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2024-05-10T10:42:47Zpaperaa:paper_01082701_v52_n4_p823_BaggioInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962024-05-10 10:42:48.212Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
spellingShingle The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
Baggio, R.
Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
title_short The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_fullStr The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full_unstemmed The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_sort The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
dc.creator.none.fl_str_mv Baggio, R.
Garland, M.T.
Perec, M.
author Baggio, R.
author_facet Baggio, R.
Garland, M.T.
Perec, M.
author_role author
author2 Garland, M.T.
Perec, M.
author2_role author
author
dc.subject.none.fl_str_mv Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
topic Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
description The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively.
publishDate 1996
dc.date.none.fl_str_mv 1996
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
url http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Acta Crystallogr Sect C Cryst Struct Commun 1996;52(4):823-826
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 15,811543

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