On-line micellar-enhanced spectrofluorimetric determination of rhodamine dye in cosmetics

A simple FI-fluorimetric analytical methodology for the continuous and sequential determination of rhodamine B (RhB) in cosmetic products has been developed and evaluated in terms of sensibility and selectivity. The influence of several surfactant solutions on RhB fluorescence signal has been studie...

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Detalles Bibliográficos
Autores: Wang, Chien Chun, Masi, Adriana Noemi, Fernandez, Liliana Patricia
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2008
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/93010
Acceso en línea:http://hdl.handle.net/11336/93010
Access Level:acceso abierto
Palabra clave:COSMETICS
FLOW INJECTION SPECTROFLUORIMETRY
MICELLES
RHODAMINE B
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descripción
Sumario:A simple FI-fluorimetric analytical methodology for the continuous and sequential determination of rhodamine B (RhB) in cosmetic products has been developed and evaluated in terms of sensibility and selectivity. The influence of several surfactant solutions on RhB fluorescence signal has been studied; particular attention was paid in the aggregation behavior of RhB-SDS system. Linear response has been obtained in the range of 1.6 × 10-9 and 1 × 10-6 mol L-1, with a detection limit of 5 × 10-10 mol L-1. The novel technique provides a simple dissolution of sample, on-line filtration with sampling rate higher than 100 samples h-1 and has been satisfactorily applied to the RhB determination in commercial lipsticks.