Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface

Detalhes bibliográficos
Autores: Fuhr, Javier Daniel, Van der Meijden, Maarten W,, Cristina, Lucila Josefina, Rodriguez, Luis Miguel, Kellogg, Richard M., Gayone, Julio Esteban, Ascolani, Hugo, Lingenfelder, Magalí Alejandra
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2017
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositório:CONICET Digital (CONICET)
Idioma:inglês
OAI Identifier:oai:ri.conicet.gov.ar:11336/30532
Acesso em linha:http://hdl.handle.net/11336/30532
Access Level:Acceso aberto
Palavra-chave:Chirality
Surfaces
Helicenes
Dft
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Descrição
Resumo:The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface

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