Self-assembled monolayers of isocyanides on nickel electrodes

Alligator clip on a nickel electrode: Monolayers of ferrocenyl-terminated isocyanides are strongly chemisorbed on nickel surfaces (see picture). The nickel-isocyanide interaction has a parallel binding mode, and the monolayers have higher thermal stability in boiling ethanol than thiol monolayers on...

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Detalhes bibliográficos
Autores: Lee, Youngu, Morales, Gustavo Marcelo, Yu, Luping
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2005
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/114815
Acesso em linha:http://hdl.handle.net/11336/114815
Access Level:acceso abierto
Palavra-chave:CHEMISORPTION
MOLECULAR DEVICES
MONOLAYERS NICKEL
SELF-ASSEMBLY
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descrição
Resumo:Alligator clip on a nickel electrode: Monolayers of ferrocenyl-terminated isocyanides are strongly chemisorbed on nickel surfaces (see picture). The nickel-isocyanide interaction has a parallel binding mode, and the monolayers have higher thermal stability in boiling ethanol than thiol monolayers on gold. The nickel-isocyanide monolayers could be useful in molecular electronics.