The structure of {[Co(pht)(bpy)(H2O)]·3H2O}n (pht is phthalate and bpy is 4,4'-bipyridine) and the role of solvent water clusters in structure stability
The CoII cation in poly[[aqua(-benzene-1,2-dicarboxylato3 O1 ,O2 :O1 )(-4,40 -bipyridine-2 N:N0 )cobalt(II)] trihydrate], {[Co(C8H4O4)(C10H8N2)(H2O)]3H2O}n, is octahedrally coordinated by two N atoms of two 4,40 -bipyridine ligands, three O atoms from phthalate anions and a fourth O atom from a coor...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2014 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/30703 |
| Acceso en línea: | http://hdl.handle.net/11336/30703 |
| Access Level: | acceso abierto |
| Palabra clave: | Crystal Structure Water Structure https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | The CoII cation in poly[[aqua(-benzene-1,2-dicarboxylato3 O1 ,O2 :O1 )(-4,40 -bipyridine-2 N:N0 )cobalt(II)] trihydrate], {[Co(C8H4O4)(C10H8N2)(H2O)]3H2O}n, is octahedrally coordinated by two N atoms of two 4,40 -bipyridine ligands, three O atoms from phthalate anions and a fourth O atom from a coordinated water molecule. The packing consists of planes of coordination polymers linked by hydrogen bonds mediated by three solvent water molecules; the linkage is achieved by the water molecules forming intricate oligomeric clusters which also involve the O atoms of the phthalate ligands. |
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