Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene

Complexes of Rh, Ru, Pd and Ni with tridecylamine and chloride as ligands were prepared and tested as heterogeneous catalysts for the hydrogenation of cyclohexene. The Wilkinson's complex was used as a reference catalyst. Supported complexes turned out to be more active and more resistant to a...

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Autores: Cagnola, Edgardo Alberto, Quiroga, Monica Esther, Liprandi, Domingo Antonio, L'argentiere, Pablo Cesar
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2004
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/74033
Acceso en línea:http://hdl.handle.net/11336/74033
Access Level:acceso abierto
Palabra clave:Catalytic Hydrogenation
Heterogeneous Catalysts
Transition Metal Complexes
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
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spelling Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexeneCagnola, Edgardo AlbertoQuiroga, Monica EstherLiprandi, Domingo AntonioL'argentiere, Pablo CesarCatalytic HydrogenationHeterogeneous CatalystsTransition Metal Complexeshttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Complexes of Rh, Ru, Pd and Ni with tridecylamine and chloride as ligands were prepared and tested as heterogeneous catalysts for the hydrogenation of cyclohexene. The Wilkinson's complex was used as a reference catalyst. Supported complexes turned out to be more active and more resistant to a sulphur poison than the homogeneous systems also evaluated for comparison. The rhodium-tridecylamine complex was the most active, slightly less than the Wilkinson's complex but more sulphur resistant than the latter. XPS and FTIR studies revealed that the complexes kept their chemical identity and remained attached to the support even after the reaction. This suggests that the coordination compounds studied are the catalytically active species or that they are converted to the actual active species during the catalytic process.Fil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; ArgentinaFil: Quiroga, Monica Esther. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; ArgentinaFil: L'argentiere, Pablo Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2004-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfhttp://hdl.handle.net/11336/74033Cagnola, Edgardo Alberto; Quiroga, Monica Esther; Liprandi, Domingo Antonio; L'argentiere, Pablo Cesar; Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene; Elsevier Science; Applied Catalysis A: General; 274; 1-2; 10-2004; 205-2120926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2004.07.001info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04006271info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:20:26Zoai:ri.conicet.gov.ar:11336/74033instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:20:27.203CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
title Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
spellingShingle Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
Cagnola, Edgardo Alberto
Catalytic Hydrogenation
Heterogeneous Catalysts
Transition Metal Complexes
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
title_short Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
title_full Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
title_fullStr Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
title_full_unstemmed Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
title_sort Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene
dc.creator.none.fl_str_mv Cagnola, Edgardo Alberto
Quiroga, Monica Esther
Liprandi, Domingo Antonio
L'argentiere, Pablo Cesar
author Cagnola, Edgardo Alberto
author_facet Cagnola, Edgardo Alberto
Quiroga, Monica Esther
Liprandi, Domingo Antonio
L'argentiere, Pablo Cesar
author_role author
author2 Quiroga, Monica Esther
Liprandi, Domingo Antonio
L'argentiere, Pablo Cesar
author2_role author
author
author
dc.subject.none.fl_str_mv Catalytic Hydrogenation
Heterogeneous Catalysts
Transition Metal Complexes
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
topic Catalytic Hydrogenation
Heterogeneous Catalysts
Transition Metal Complexes
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
description Complexes of Rh, Ru, Pd and Ni with tridecylamine and chloride as ligands were prepared and tested as heterogeneous catalysts for the hydrogenation of cyclohexene. The Wilkinson's complex was used as a reference catalyst. Supported complexes turned out to be more active and more resistant to a sulphur poison than the homogeneous systems also evaluated for comparison. The rhodium-tridecylamine complex was the most active, slightly less than the Wilkinson's complex but more sulphur resistant than the latter. XPS and FTIR studies revealed that the complexes kept their chemical identity and remained attached to the support even after the reaction. This suggests that the coordination compounds studied are the catalytically active species or that they are converted to the actual active species during the catalytic process.
publishDate 2004
dc.date.none.fl_str_mv 2004-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74033
Cagnola, Edgardo Alberto; Quiroga, Monica Esther; Liprandi, Domingo Antonio; L'argentiere, Pablo Cesar; Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene; Elsevier Science; Applied Catalysis A: General; 274; 1-2; 10-2004; 205-212
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74033
identifier_str_mv Cagnola, Edgardo Alberto; Quiroga, Monica Esther; Liprandi, Domingo Antonio; L'argentiere, Pablo Cesar; Immobilized Rh, Ru, Pd and Ni complexes as catalysts in the hydrogenation of cyclohexene; Elsevier Science; Applied Catalysis A: General; 274; 1-2; 10-2004; 205-212
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2004.07.001
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04006271
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/msword
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15.811543

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