Voltammetric quantification of 4-nitrophenol using a multivariate optimized plated bismuth film electrode
In this study the multivariate optimization of bismuth film deposition (BiFE) on glassy carbon electrode, together with square wave voltammetry parameters for nitrophenol quantification, is described for the first time. For this purpose, response surface methodology and desirability function were ap...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2019 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/124177 |
| Acceso en línea: | http://hdl.handle.net/11336/124177 |
| Access Level: | acceso abierto |
| Palabra clave: | Bismuth film electrode BoxBehnken design Response Surface Methodology Nitrophenol https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | In this study the multivariate optimization of bismuth film deposition (BiFE) on glassy carbon electrode, together with square wave voltammetry parameters for nitrophenol quantification, is described for the first time. For this purpose, response surface methodology and desirability function were applied to a Box-Behnken design. For the BiFE deposition procedure, the relationship between the reduction current peak (ip) and standard deviation values with time, potential deposition, and Bi(III) concentration were analyzed; meanwhile, for frequency, step, and amplitude only the relationship with ip was considered. The pH influence in nitrophenol determination was carried on by univariate analysis. After parameters optimization a limit of detection of 3.4 × 10-6 mol L-1 was observed. |
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