Electrochemical oxidation of iodide dissolved in sodium-nitrate-potassium-nitrate eutectic melt on a platinum rotating disk electrode

The E/I curve related to the electrochemical oxidation of iodide dissolved in molten nitrates on a platinum rotating disk electrode involves two anodic waves. The first corresponds to a reversible two-electron process and the second to a reversible one-electron process. A definite ratio between the...

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Detalles Bibliográficos
Autores: Triaca, Walter Enrique, Videla, Héctor A., Arvia, Alejandro Jorge
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1971
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/119491
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/119491
Access Level:acceso abierto
Palabra clave:Ciencias Exactas
Química
Iodide
Electrochemical oxidation
Anodic wave
Descripción
Sumario:The E/I curve related to the electrochemical oxidation of iodide dissolved in molten nitrates on a platinum rotating disk electrode involves two anodic waves. The first corresponds to a reversible two-electron process and the second to a reversible one-electron process. A definite ratio between the anodic limiting currents is established suggesting that the second anodic wave is not independent from the first one. The parameters related to the diffusion of the species participating in the reaction are evaluated.