Effect of particle size in the hydrogenation of crotonaldehyde on supported Pt and Pt-Sn catalysts

The present work reports the effect of metal particle size on the selectivity to crotyl alcohol (SUOL) in the liquid phase hydrogenation of crotonaldehyde over SiO2 and a-Al2O3-supported Pt and Pt-Sn catalysts. It was demonstrated that, for the monometallic catalysts, a higher particle size led to a...

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Detalles Bibliográficos
Autores: Santori, Gerardo Fabián, Casella, Mónica Laura, Siri, Guillermo Jorge, Aduriz, Hugo R., Ferretti, Osmar
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2002
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:español
OAI Identifier:oai:sedici.unlp.edu.ar:10915/138158
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/138158
Access Level:acceso abierto
Palabra clave:Ciencias Exactas
Crotonaldehyde hydrogenation
Pt-Sn catalysts
particle size effect
Descripción
Sumario:The present work reports the effect of metal particle size on the selectivity to crotyl alcohol (SUOL) in the liquid phase hydrogenation of crotonaldehyde over SiO2 and a-Al2O3-supported Pt and Pt-Sn catalysts. It was demonstrated that, for the monometallic catalysts, a higher particle size led to a higher SUOL, while for the bimetallic catalysts, this effect was not so important.