The infrared spectrum of [Ni(H<SUB>2</SUB>O)<SUB>4</SUB>][VOPO<SUB>4</SUB>]<SUB>2</SUB>

While phosphato-vanadates, containing vanadium (V) have been extensively investigated [1, 2], similar phases with vanadium (IV) have received attention only recently [3-6]. These materials have a very rich and complex structural chemistry and present interesting intercalculation and catalytic proper...

Descripción completa

Detalles Bibliográficos
Autores: Baran, Enrique José, Lii, K. H., Wu, L. S.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1995
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/133124
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/133124
Access Level:acceso abierto
Palabra clave:Química
Descripción
Sumario:While phosphato-vanadates, containing vanadium (V) have been extensively investigated [1, 2], similar phases with vanadium (IV) have received attention only recently [3-6]. These materials have a very rich and complex structural chemistry and present interesting intercalculation and catalytic properties [7-9]. Therefore, and with the aim to advance the general characterization of this type of compounds, we have initiated systematic studies of their vibrational properties [10-12]. In the present paper we report the results of an IR-spectroscopic study of [Ni(H<SUB>2</SUB>O)<SUB>4</SUB>][VOPO<SUB>4</SUB>]<SUB>2</SUB>.