Novel Cyclic Enaminone Esters and N-Heterocycles by Divergent Chemical Behavior through Amine-Mediated Reactions
New acridinones and enaminone esters were synthesized by microwave-assisted tandem-Michael-Michael addition and cyclization from cyclohexane-1,3-diones. The reaction mechanism for both open and closed structures, and the presence of intramolecular twelve-membered rings derived from NH and OH H-bonds...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2015 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/37926 |
| Acceso en línea: | http://hdl.handle.net/11336/37926 |
| Access Level: | acceso abierto |
| Palabra clave: | Acridines, Decahydrodioxo- Cycloadditions Enaminones Intramolecular H-Bonding Michael-Michael Reaction Microwave-Assisted Reactions https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | New acridinones and enaminone esters were synthesized by microwave-assisted tandem-Michael-Michael addition and cyclization from cyclohexane-1,3-diones. The reaction mechanism for both open and closed structures, and the presence of intramolecular twelve-membered rings derived from NH and OH H-bonds of enaminone esters are discussed. |
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