Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite

Significance of effective conversion of methane (C1) to more valuable compounds such as aromatics is studied using n-hexane (C6) as co-reactant. AH yield was as high as 30 mol% C using the following reaction conditions: temperature, 500 C; contact time w=f ¼30 g h mol 1 and a C1 molar fraction, XC1:...

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Autores: Anunziata, Oscar Alfredo, González Mercado, Griselda Verónica, Pierella, Liliana Beatriz
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2004
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/40586
Acceso en línea:http://hdl.handle.net/11336/40586
Access Level:acceso abierto
Palabra clave:Zn/Hzsm-11
Methane Activation
Hexane as Co-Reactan
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
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repository_id_str
spelling Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeoliteAnunziata, Oscar AlfredoGonzález Mercado, Griselda VerónicaPierella, Liliana BeatrizZn/Hzsm-11Methane ActivationHexane as Co-Reactanhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Significance of effective conversion of methane (C1) to more valuable compounds such as aromatics is studied using n-hexane (C6) as co-reactant. AH yield was as high as 30 mol% C using the following reaction conditions: temperature, 500 C; contact time w=f ¼30 g h mol 1 and a C1 molar fraction, XC1: ¼(C1/C1 +C6)¼0.60, was achieved. The effect of the contact time, molar fraction, and time on stream was analyzed in order to obtain more information about different species evolution. The C1 conversion reached at 50 mol% C using Zn/HZSM-11 with 2.13 mol Zn per cell unit.Fil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: González Mercado, Griselda Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaElsevier Science2004-08-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40586Anunziata, Oscar Alfredo; González Mercado, Griselda Verónica; Pierella, Liliana Beatriz; Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite; Elsevier Science; Catalysis Communications; 5; 8; 9-8-2004; 401-4051566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736704000846info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2004.04.008info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:35:38Zoai:ri.conicet.gov.ar:11336/40586instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:35:38.633CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
title Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
spellingShingle Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
Anunziata, Oscar Alfredo
Zn/Hzsm-11
Methane Activation
Hexane as Co-Reactan
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
title_full Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
title_fullStr Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
title_full_unstemmed Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
title_sort Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite
dc.creator.none.fl_str_mv Anunziata, Oscar Alfredo
González Mercado, Griselda Verónica
Pierella, Liliana Beatriz
author Anunziata, Oscar Alfredo
author_facet Anunziata, Oscar Alfredo
González Mercado, Griselda Verónica
Pierella, Liliana Beatriz
author_role author
author2 González Mercado, Griselda Verónica
Pierella, Liliana Beatriz
author2_role author
author
dc.subject.none.fl_str_mv Zn/Hzsm-11
Methane Activation
Hexane as Co-Reactan
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic Zn/Hzsm-11
Methane Activation
Hexane as Co-Reactan
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description Significance of effective conversion of methane (C1) to more valuable compounds such as aromatics is studied using n-hexane (C6) as co-reactant. AH yield was as high as 30 mol% C using the following reaction conditions: temperature, 500 C; contact time w=f ¼30 g h mol 1 and a C1 molar fraction, XC1: ¼(C1/C1 +C6)¼0.60, was achieved. The effect of the contact time, molar fraction, and time on stream was analyzed in order to obtain more information about different species evolution. The C1 conversion reached at 50 mol% C using Zn/HZSM-11 with 2.13 mol Zn per cell unit.
publishDate 2004
dc.date.none.fl_str_mv 2004-08-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/40586
Anunziata, Oscar Alfredo; González Mercado, Griselda Verónica; Pierella, Liliana Beatriz; Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite; Elsevier Science; Catalysis Communications; 5; 8; 9-8-2004; 401-405
1566-7367
CONICET Digital
CONICET
url http://hdl.handle.net/11336/40586
identifier_str_mv Anunziata, Oscar Alfredo; González Mercado, Griselda Verónica; Pierella, Liliana Beatriz; Improvement of methane activation using n-hexane as co-reactant over Zn/HZSM-11 zeolite; Elsevier Science; Catalysis Communications; 5; 8; 9-8-2004; 401-405
1566-7367
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736704000846
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2004.04.008
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15,811543

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