2,4-Dinitrophenyl phenyl sulfone

The crystal structure of the title compound, C12H8-N2O6S, has been determined by single-crystal X-ray diffraction. The compound crystallizes in the noncentrosymmetric P21 space group. The substituted aromatic ring has a slightly deformed boat conformation. The ο-NO2 and p-NO2 groups are twisted out...

ver descrição completa

Detalhes bibliográficos
Autores: Ellena, J., Punte, G., Nudelman, N.S.
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:1996
País:Argentina
Recursos:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
Repositório:Biblioteca Digital (UBA-FCEN)
Idioma:inglês
OAI Identifier:paperaa:paper_01082701_v52_n11_p2929_Ellena
Acesso em linha:http://hdl.handle.net/20.500.12110/paper_01082701_v52_n11_p2929_Ellena
Access Level:Acceso aberto
Palavra-chave:Bond strength (chemical)
Chemical bonds
Conformations
Crystal structure
Molecular structure
Single crystals
Sulfur compounds
X ray crystallography
Boat conformations
Phenyl ring
Aromatic compounds
Descrição
Resumo:The crystal structure of the title compound, C12H8-N2O6S, has been determined by single-crystal X-ray diffraction. The compound crystallizes in the noncentrosymmetric P21 space group. The substituted aromatic ring has a slightly deformed boat conformation. The ο-NO2 and p-NO2 groups are twisted out of the plane of the phenyl ring. The unsubstituted aromatic ring is planar and the dihedral angle between the mean plane of the rings is 71.1 (2)○. Short C - H⋯O intermolecular contacts stabilize the three-dimensional structure.