Metsulfuron-methyl and glyphosate transport in a mollisol soil in the Pampean region of Argentina

The agricultural activity poses the potential risk of contaminating groundwater resources because of the leaching capacity of the agrochemicals used. Glyphosate and metsulfuron-methyl are two herbicides widely used in the Pampean region of Argentina. The objective of this study was to evaluate the v...

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Detalles Bibliográficos
Autores: Gonzalo Mayoral, Eliana Soledad, Aparicio, Virginia Carolina, De Geronimo, Eduardo, Costa, José Luis
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:Argentina
Institución:Instituto Nacional de Tecnología Agropecuaria
Repositorio:INTA Digital (INTA)
Idioma:inglés
OAI Identifier:oai:localhost:20.500.12123/10940
Acceso en línea:http://hdl.handle.net/20.500.12123/10940
http://www.se.org.pk/Papers.aspx?issueid=85
http://dx.doi.org/10.25252/SE/2021/202578
Access Level:acceso abierto
Palabra clave:Suelo
Procesos de Transporte en el Suelo
Aguas Subterráneas
Lixiviación
Flujo del Suelo
Herbicidas
Argentina
Soil
Soil Transport Processes
Groundwater
Leaching
Slipping of Soil
Herbicides
Descripción
Sumario:The agricultural activity poses the potential risk of contaminating groundwater resources because of the leaching capacity of the agrochemicals used. Glyphosate and metsulfuron-methyl are two herbicides widely used in the Pampean region of Argentina. The objective of this study was to evaluate the vertical transport of both herbicides in the soil profile of a typic Argiudoll, under laboratory conditions. Bromide (equivalent to 1500 kg ha-1) was used as a non-reactive solute, and metsulfuron-methyl (equivalent to 10 g ha-1 of the active ingredient, a.i.) and glyphosate (equivalent to 5 kg ha-1 of a.i.) were used as reactive solutes. Six replicates per horizon were used. The transport parameters were estimated using the convection-dispersion equation (CDE) and analysed using mixed models. A preferential flow by macropores was the mechanism dominating the transport of the substances in the horizons under study. The following recovery percentages were found in effluents: bromide 72.4, 83.75 and 90.49%, metsulfuron-methyl 51.7, 56.5 and 67.0%, and glyphosate 0.75, 1.76 and 0% in horizons A, B and C, respectively. Metsulfuron-methyl presented higher leaching capacity in the horizons studied than glyphosate, which was retained in the first centimetres of each column. Thus, metsulfuron-methyl poses a high potential risk of contaminating groundwater, as opposed to glyphosate, which involves a low to negligible risk.