Five-Membered aromatic heterocycles in diels-alder cycloaddition reactions: Theoretical Studies as a Complement of the Experimental Researches
The dienophilic behavior of electron-deficient substituted five-membered aromatic heterocyclices in polar cycloaddition reactions is studied from a theoretical point of view employing the global electrophilicity index to estimate the electrophilic character of the dienophiles and to compare them wit...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2011 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/74628 |
| Acceso en línea: | http://hdl.handle.net/11336/74628 |
| Access Level: | acceso abierto |
| Palabra clave: | Dienophiles Electrophilicity Index Five-Membered Aromatic Heterocycles Polar-Diels-Alder https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | The dienophilic behavior of electron-deficient substituted five-membered aromatic heterocyclices in polar cycloaddition reactions is studied from a theoretical point of view employing the global electrophilicity index to estimate the electrophilic character of the dienophiles and to compare them with the available experimental information. The type of substitution on the heteroatomic ring is also discussed. Complementary some new reactions of these substrates are described. |
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