One-step preparation of UV transparent highly ordered mesoporous zirconia thin films

Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants ca...

Descripción completa

Detalles Bibliográficos
Autores: Zelcer, Andrés, Soler Illia, Galo Juan de Avila Arturo
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/77856
Acceso en línea:http://hdl.handle.net/11336/77856
Access Level:acceso abierto
Palabra clave:Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
id AR_7e1c00a3ad16f9be20b9288ff3c99cb1
oai_identifier_str oai:ri.conicet.gov.ar:11336/77856
network_acronym_str AR
network_name_str Argentina
repository_id_str
spelling One-step preparation of UV transparent highly ordered mesoporous zirconia thin filmsZelcer, AndrésSoler Illia, Galo Juan de Avila ArturoMesoporous Thin FilmsZirconiaMultilayer Thin FilmsAcetylacetonatehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.Fil: Zelcer, Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaRoyal Society of Chemistry2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77856Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo; One-step preparation of UV transparent highly ordered mesoporous zirconia thin films; Royal Society of Chemistry; Journal of Materials Chemistry C; 1; 7; 1-2013; 1359-13672050-7526CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2013/TC/c2tc00319hinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C2TC00319Hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:53:58Zoai:ri.conicet.gov.ar:11336/77856instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:53:58.765CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
spellingShingle One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
Zelcer, Andrés
Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
title_short One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_full One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_fullStr One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_full_unstemmed One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
title_sort One-step preparation of UV transparent highly ordered mesoporous zirconia thin films
dc.creator.none.fl_str_mv Zelcer, Andrés
Soler Illia, Galo Juan de Avila Arturo
author Zelcer, Andrés
author_facet Zelcer, Andrés
Soler Illia, Galo Juan de Avila Arturo
author_role author
author2 Soler Illia, Galo Juan de Avila Arturo
author2_role author
dc.subject.none.fl_str_mv Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
topic Mesoporous Thin Films
Zirconia
Multilayer Thin Films
Acetylacetonate
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
description Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77856
Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo; One-step preparation of UV transparent highly ordered mesoporous zirconia thin films; Royal Society of Chemistry; Journal of Materials Chemistry C; 1; 7; 1-2013; 1359-1367
2050-7526
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77856
identifier_str_mv Zelcer, Andrés; Soler Illia, Galo Juan de Avila Arturo; One-step preparation of UV transparent highly ordered mesoporous zirconia thin films; Royal Society of Chemistry; Journal of Materials Chemistry C; 1; 7; 1-2013; 1359-1367
2050-7526
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2013/TC/c2tc00319h
info:eu-repo/semantics/altIdentifier/doi/10.1039/C2TC00319H
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799195485792108544
score 15,81155

Similares en LA Referencia