Estudio comparativo entre la difusión de Uranio en Zry-4 y en Zr-α puro

Throughout the α-spectrometry U diffusion in pure Zry-4 was studied and compared with pure α-Zr in the temperature range 843-1093 K in order to analyze the diffusion process in both matrices. D values are syste-matically higher in Zry-4 and its temperature dependence obeys the Arrhenius law being: D...

Descripción completa

Detalles Bibliográficos
Autores: Perez, Rodolfo Ariel, Gordillo, Jorge Apostol, Iribarren, Manuel José, Di Lalla, Nicolás
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:español
OAI Identifier:oai:ri.conicet.gov.ar:11336/117543
Acceso en línea:http://hdl.handle.net/11336/117543
Access Level:acceso abierto
Palabra clave:DIFFUSION
ALPHA-SPECTROMETRY
URANIUM
ZIRCONIUM
ZIRCALOY
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
Descripción
Sumario:Throughout the α-spectrometry U diffusion in pure Zry-4 was studied and compared with pure α-Zr in the temperature range 843-1093 K in order to analyze the diffusion process in both matrices. D values are syste-matically higher in Zry-4 and its temperature dependence obeys the Arrhenius law being: D0 = (3,2 ± 1,1) m2/s and Q = (316 ± 9) kJ mol-1, whereas in α-Zr U diffusion present an apart to this law, consistent in a downward curvature in the ln(D) vs 1/T plot. Below 873 K U solubility in Zry4 is lower than in pure Zr.