Triggering gold nanoparticles formation on a quartz surface by nanosecond pulsed laser irradiation

A new direct and straightforward method is proposed to synthesize bare Au nanoparticles (Au NPs) on a quartz surface by nanosecond 532 nm pulsed laser irradiation of a quartz surface in contact with Au(iii) precursor solution. The characterisation by XPS, UV-Vis, SEM and AFM measurements demonstrate...

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Detalles Bibliográficos
Autores: Mercadal, Pablo Agustin, García Schejtman, Sergio David, Cometto, Fernando Pablo, Veglia, Alicia Viviana, Coronado, Eduardo A.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/172542
Acceso en línea:http://hdl.handle.net/11336/172542
Access Level:acceso abierto
Palabra clave:Au_NPs
SERS
XPS
QUARTZ
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descripción
Sumario:A new direct and straightforward method is proposed to synthesize bare Au nanoparticles (Au NPs) on a quartz surface by nanosecond 532 nm pulsed laser irradiation of a quartz surface in contact with Au(iii) precursor solution. The characterisation by XPS, UV-Vis, SEM and AFM measurements demonstrate the formation of bare Au NPs anchored on the quartz surface with a mean height of 27 ± 10 nm localized in the laser irradiation area. The main features of this approach are their simplicity, quick fabrication and the large surface area covered by Au NPs. The absence of ligands/stabilizing agents on the Au NPs makes this substrate very suitable for its direct surface modification opening the range of applications in biology, medicine, sensing, catalysis, among others. As a proof of concept, the capabilities and advantages of this substrate as Surface Enhanced Raman Spectroscopy (SERS) platform were tested demonstrating the absence of any Raman signal overlapping with the analyte in the whole spectral range.