Flow behavior and syneresis of ball milled rice starch and their correlations with starch structure

The effects of milling energy (0.26–4.08 kJ/g) on starch structure, flow behavior and syneresis of starch dispersions (4–8% w/v) were investigated. Crystallinity loss of starch (XRD analysis) during milling could be mathematically related with the increase of 1047 cm−1/1022 cm−1 FT-IR intensity rati...

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Detalhes bibliográficos
Autores: González, Luciana Carla, Loubes, María Ana, Bertotto, María M., Baeza, Rosa Isabel, Tolaba, Marcela Patricia
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/181176
Acesso em linha:http://hdl.handle.net/11336/181176
Access Level:acceso abierto
Palavra-chave:BALL MILLING
FT-IR SPECTROSCOPY
PSEUDOPLASTIC BEHAVIOR
RICE STARCH
STARCH STRUCTURE
VISCOSITY
https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
Descrição
Resumo:The effects of milling energy (0.26–4.08 kJ/g) on starch structure, flow behavior and syneresis of starch dispersions (4–8% w/v) were investigated. Crystallinity loss of starch (XRD analysis) during milling could be mathematically related with the increase of 1047 cm−1/1022 cm−1 FT-IR intensity ratio (Ri) and it was also reflected by the changes in the shape and surface roughness of starch granules (SEM micrographs). Starch dispersions showed a Newtonian or pseudoplastic flow pattern dependent on starch concentration and milling energy. Consistency of starch dispersions (4 and 6%) remained constant during refrigerated storage only for severely milled starch. Syneresis diminished with increasing milling energy and starch concentration; it could be minimized (4% and 4.08 kJ/g) or completely eliminated (8% and 1.04 kJ/g). Significant correlations of Ri with consistency index and syneresis were found. Ball milling notably improved the suitability of starch as an ingredient in fluid or viscous foodstuffs.