Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative

The UV irradiation of a hexane solution of the complex (h5 -C5Me4(CH2)2NMe2)Re(CO)3 (1) afforded the chelated species (h5 :h1 -C5Me4(CH2)2NMe2)Re(CO)2 (2). The molecular structure of 2 has been determined by X-ray crystallography. The reaction of 2 with two-electron donor ligands yields (h5 - C5Me4(...

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Autores: Godoy, Fernando, Gómez, Alejandra, Segura, Rodrigo, Doctorovich, Fabio, Pellegrino, Juan, Gaviglio, Carina del Valle, Guerrero, Paulina, Klahn, A. Hugo, Fuentealba, Mauricio, Garland, María Teresa
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/31816
Acceso en línea:http://hdl.handle.net/11336/31816
Access Level:acceso abierto
Palabra clave:Rhenium
Nitrosyl
Cyclopentadienyl Functionalized
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
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network_acronym_str AR
network_name_str Argentina
repository_id_str
dc.title.none.fl_str_mv Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
title Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
spellingShingle Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
Godoy, Fernando
Rhenium
Nitrosyl
Cyclopentadienyl Functionalized
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
title_full Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
title_fullStr Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
title_full_unstemmed Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
title_sort Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
dc.creator.none.fl_str_mv Godoy, Fernando
Gómez, Alejandra
Segura, Rodrigo
Doctorovich, Fabio
Pellegrino, Juan
Gaviglio, Carina del Valle
Guerrero, Paulina
Klahn, A. Hugo
Fuentealba, Mauricio
Garland, María Teresa
author Godoy, Fernando
author_facet Godoy, Fernando
Gómez, Alejandra
Segura, Rodrigo
Doctorovich, Fabio
Pellegrino, Juan
Gaviglio, Carina del Valle
Guerrero, Paulina
Klahn, A. Hugo
Fuentealba, Mauricio
Garland, María Teresa
author_role author
author2 Gómez, Alejandra
Segura, Rodrigo
Doctorovich, Fabio
Pellegrino, Juan
Gaviglio, Carina del Valle
Guerrero, Paulina
Klahn, A. Hugo
Fuentealba, Mauricio
Garland, María Teresa
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Rhenium
Nitrosyl
Cyclopentadienyl Functionalized
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic Rhenium
Nitrosyl
Cyclopentadienyl Functionalized
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description The UV irradiation of a hexane solution of the complex (h5 -C5Me4(CH2)2NMe2)Re(CO)3 (1) afforded the chelated species (h5 :h1 -C5Me4(CH2)2NMe2)Re(CO)2 (2). The molecular structure of 2 has been determined by X-ray crystallography. The reaction of 2 with two-electron donor ligands yields (h5 - C5Me4(CH2)2NMe2)Re(CO)2(L) (1, L ¼ CO; 3, L ¼ PMe3). The chelated species 2 also reacts with MeOTf, HBF4, and I2 to form the cationic compounds trans-[(h5 -C5Me4(CH2)2NMe2)Re(CO)2X]þ ([4]D, X ¼ Me; [5]D, X ¼ H; [6]D, X ¼ I). The trans stereochemistry of 4e6 have been assigned on the basis of n(CO) IR intensities and 13C NMR spectroscopy. Also, complex 2 reacts with nitrosyl tetrafluoroborate to yield [(h5 - C5Me4(CH2)2NMe2NO)Re(CO)2(NO)]BF4 ([7]2D). The redox behavior of the {ReNO}6 complex [7]2D was studied and the products obtained after two-electron reduction were characterized by IR. DFT calculations were done to optimize the structure of [7]2D and to study the effect of the sidearm coordination on the electronic structure of a cyclopentadienyl {ReNO}8 complex.
publishDate 2014
dc.date.none.fl_str_mv 2014-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31816
Garland, María Teresa; Fuentealba, Mauricio; Klahn, A. Hugo; Guerrero, Paulina; Gaviglio, Carina del Valle; Pellegrino, Juan; et al.; Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative; Elsevier Science Sa; Journal of Organometallic Chemistry; 765; 5-2014; 8-16
0022-328X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31816
identifier_str_mv Garland, María Teresa; Fuentealba, Mauricio; Klahn, A. Hugo; Guerrero, Paulina; Gaviglio, Carina del Valle; Pellegrino, Juan; et al.; Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative; Elsevier Science Sa; Journal of Organometallic Chemistry; 765; 5-2014; 8-16
0022-328X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jorganchem.2014.04.019
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022328X14001892
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799195829245837312
spelling Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivativeGodoy, FernandoGómez, AlejandraSegura, RodrigoDoctorovich, FabioPellegrino, JuanGaviglio, Carina del ValleGuerrero, PaulinaKlahn, A. HugoFuentealba, MauricioGarland, María TeresaRheniumNitrosylCyclopentadienyl Functionalizedhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The UV irradiation of a hexane solution of the complex (h5 -C5Me4(CH2)2NMe2)Re(CO)3 (1) afforded the chelated species (h5 :h1 -C5Me4(CH2)2NMe2)Re(CO)2 (2). The molecular structure of 2 has been determined by X-ray crystallography. The reaction of 2 with two-electron donor ligands yields (h5 - C5Me4(CH2)2NMe2)Re(CO)2(L) (1, L ¼ CO; 3, L ¼ PMe3). The chelated species 2 also reacts with MeOTf, HBF4, and I2 to form the cationic compounds trans-[(h5 -C5Me4(CH2)2NMe2)Re(CO)2X]þ ([4]D, X ¼ Me; [5]D, X ¼ H; [6]D, X ¼ I). The trans stereochemistry of 4e6 have been assigned on the basis of n(CO) IR intensities and 13C NMR spectroscopy. Also, complex 2 reacts with nitrosyl tetrafluoroborate to yield [(h5 - C5Me4(CH2)2NMe2NO)Re(CO)2(NO)]BF4 ([7]2D). The redox behavior of the {ReNO}6 complex [7]2D was studied and the products obtained after two-electron reduction were characterized by IR. DFT calculations were done to optimize the structure of [7]2D and to study the effect of the sidearm coordination on the electronic structure of a cyclopentadienyl {ReNO}8 complex.Fil: Godoy, Fernando. Universidad de Santiago de Chile; ChileFil: Gómez, Alejandra. Universidad de Santiago de Chile; ChileFil: Segura, Rodrigo. Universidad de Santiago de Chile; ChileFil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Pellegrino, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Gaviglio, Carina del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Guerrero, Paulina. Pontificia Universidad Católica de Valparaíso; ChileFil: Klahn, A. Hugo. Pontificia Universidad Católica de Valparaíso; ChileFil: Fuentealba, Mauricio. Pontificia Universidad Católica de Valparaíso; ChileFil: Garland, María Teresa. Universidad de Chile; ChileElsevier Science Sa2014-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31816Garland, María Teresa; Fuentealba, Mauricio; Klahn, A. Hugo; Guerrero, Paulina; Gaviglio, Carina del Valle; Pellegrino, Juan; et al.; Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative; Elsevier Science Sa; Journal of Organometallic Chemistry; 765; 5-2014; 8-160022-328XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jorganchem.2014.04.019info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022328X14001892info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:05:13Zoai:ri.conicet.gov.ar:11336/31816instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:05:13.655CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
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