Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat

The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its dep...

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Authors: Ferrer, Evelina Gloria, Etcheverry, Susana Beatriz, Baran, Enrique José
Format: article
Status:Published version
Publication Date:1993
Country:Argentina
Institution:Universidad Nacional de La Plata
Repository:SEDICI (UNLP)
Language:indefinido
OAI Identifier:oai:sedici.unlp.edu.ar:10915/146414
Online Access:http://sedici.unlp.edu.ar/handle/10915/146414
Access Level:Open access
Keyword:Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
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spelling Darstellung und Eigenschaften von Vanadyl(IV)-SaccharinatFerrer, Evelina GloriaEtcheverry, Susana BeatrizBaran, Enrique JoséQuímicaVanadyl(IV) saccharinateIR spectraElectronic spectraMagnetic and thermal behaviourThe synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.Facultad de Ciencias Exactas1993-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf355-366http://sedici.unlp.edu.ar/handle/10915/146414undinfo:eu-repo/semantics/altIdentifier/issn/0026-9247info:eu-repo/semantics/altIdentifier/issn/1434-4475info:eu-repo/semantics/altIdentifier/issn/0343-7329info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00814132info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2024-05-08T13:10:50Zoai:sedici.unlp.edu.ar:10915/146414Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292024-05-08 13:10:50.426SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
spellingShingle Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
Ferrer, Evelina Gloria
Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
title_short Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_full Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_fullStr Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_full_unstemmed Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_sort Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
dc.creator.none.fl_str_mv Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
author Ferrer, Evelina Gloria
author_facet Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
author_role author
author2 Etcheverry, Susana Beatriz
Baran, Enrique José
author2_role author
author
dc.subject.none.fl_str_mv Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
topic Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
description The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
publishDate 1993
dc.date.none.fl_str_mv 1993-04-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146414
url http://sedici.unlp.edu.ar/handle/10915/146414
dc.language.none.fl_str_mv und
language und
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0026-9247
info:eu-repo/semantics/altIdentifier/issn/1434-4475
info:eu-repo/semantics/altIdentifier/issn/0343-7329
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00814132
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
355-366
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 15,811543

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