Microwave-assisted asymmetric Diels-Alder reaction using chiral auxiliaries derived from biomass
Microwave-assisted asymmetric Diels-Alder reactions using levoglucosenone-derived chiral auxiliaries have been investigated. The cycloaddition reaction between the corresponding chiral acrylate and cyclopentadiene showed important rate enhancements under microwave irradiation compared to conventiona...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2011 |
| País: | Argentina |
| Institución: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/133974 |
| Acceso en línea: | http://hdl.handle.net/11336/133974 |
| Access Level: | acceso abierto |
| Palabra clave: | ACRYLATES ASYMMETRIC SYNTHESIS DIELS-ALDER LEVOGLUCOSENONE MICROWAVES https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| Sumario: | Microwave-assisted asymmetric Diels-Alder reactions using levoglucosenone-derived chiral auxiliaries have been investigated. The cycloaddition reaction between the corresponding chiral acrylate and cyclopentadiene showed important rate enhancements under microwave irradiation compared to conventional heating conditions, whereas the yields and diastereoselectivities were not significantly affected. |
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