Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2

Rate constants have been calculated using quasi-classical trajectories (QCT) for the vibrational relaxation of highly excited O2:O2(X3Σḡ, vi) + O2(X3Σḡ,0) → O2(X3Σḡ, vf) + O2(X3Σḡ) with 22 ≤vi≤28. The present full-dimensional QCT results agree very well with recent quantum reduced dimensionality cal...

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Detalles Bibliográficos
Autores: Campos-Martínez, José, Carmona-Novillo, Estela, Echave, Julián, Hernández, Marta I., Palma, Juliana Isabel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2000
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/71682
Acceso en línea:http://hdl.handle.net/11336/71682
Access Level:acceso abierto
Palabra clave:Reaction Dynamics
Vibrational Relaxation
Gas Phase Reactions
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
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spelling Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2Campos-Martínez, JoséCarmona-Novillo, EstelaEchave, JuliánHernández, Marta I.Palma, Juliana IsabelReaction DynamicsVibrational RelaxationGas Phase Reactionshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Rate constants have been calculated using quasi-classical trajectories (QCT) for the vibrational relaxation of highly excited O2:O2(X3Σḡ, vi) + O2(X3Σḡ,0) → O2(X3Σḡ, vf) + O2(X3Σḡ) with 22 ≤vi≤28. The present full-dimensional QCT results agree very well with recent quantum reduced dimensionality calculations, giving further support to the hypothesis that the observed experimental jump in depletion rates would be due partially to enhanced vibrational relaxation. © 2000 Taylor & Francis Group, LLC.Fil: Campos-Martínez, José. Instituto de Matemática y Física Fundamental; EspañaFil: Carmona-Novillo, Estela. Instituto de Matemática y Física Fundamental; EspañaFil: Echave, Julián. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Centro de Estudios e Investigación; ArgentinaFil: Hernández, Marta I.. Instituto de Matemática y Física Fundamental; EspañaFil: Palma, Juliana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes. Centro de Estudios e Investigación; ArgentinaTaylor & Francis Ltd2000-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71682Campos-Martínez, José; Carmona-Novillo, Estela; Echave, Julián; Hernández, Marta I.; Palma, Juliana Isabel; Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2; Taylor & Francis Ltd; Molecular Physics; 98; 21; 12-2000; 1729-17350026-8976CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/00268970009483377info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00268970009483377info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:14:52Zoai:ri.conicet.gov.ar:11336/71682instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:14:53.255CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
title Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
spellingShingle Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
Campos-Martínez, José
Reaction Dynamics
Vibrational Relaxation
Gas Phase Reactions
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
title_full Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
title_fullStr Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
title_full_unstemmed Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
title_sort Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2
dc.creator.none.fl_str_mv Campos-Martínez, José
Carmona-Novillo, Estela
Echave, Julián
Hernández, Marta I.
Palma, Juliana Isabel
author Campos-Martínez, José
author_facet Campos-Martínez, José
Carmona-Novillo, Estela
Echave, Julián
Hernández, Marta I.
Palma, Juliana Isabel
author_role author
author2 Carmona-Novillo, Estela
Echave, Julián
Hernández, Marta I.
Palma, Juliana Isabel
author2_role author
author
author
author
dc.subject.none.fl_str_mv Reaction Dynamics
Vibrational Relaxation
Gas Phase Reactions
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic Reaction Dynamics
Vibrational Relaxation
Gas Phase Reactions
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description Rate constants have been calculated using quasi-classical trajectories (QCT) for the vibrational relaxation of highly excited O2:O2(X3Σḡ, vi) + O2(X3Σḡ,0) → O2(X3Σḡ, vf) + O2(X3Σḡ) with 22 ≤vi≤28. The present full-dimensional QCT results agree very well with recent quantum reduced dimensionality calculations, giving further support to the hypothesis that the observed experimental jump in depletion rates would be due partially to enhanced vibrational relaxation. © 2000 Taylor & Francis Group, LLC.
publishDate 2000
dc.date.none.fl_str_mv 2000-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/71682
Campos-Martínez, José; Carmona-Novillo, Estela; Echave, Julián; Hernández, Marta I.; Palma, Juliana Isabel; Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2; Taylor & Francis Ltd; Molecular Physics; 98; 21; 12-2000; 1729-1735
0026-8976
CONICET Digital
CONICET
url http://hdl.handle.net/11336/71682
identifier_str_mv Campos-Martínez, José; Carmona-Novillo, Estela; Echave, Julián; Hernández, Marta I.; Palma, Juliana Isabel; Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2; Taylor & Francis Ltd; Molecular Physics; 98; 21; 12-2000; 1729-1735
0026-8976
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/00268970009483377
info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00268970009483377
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15,812429

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